What exactly does the .join() method do?

I’m pretty new to Python and am completely confused by .join() which I have read is the preferred method for concatenating strings.

I tried:

strid = repr(595)
print array.array('c', random.sample(string.ascii_letters, 20 - len(strid)))
    .tostring().join(strid)

and got something like:

5wlfgALGbXOahekxSs9wlfgALGbXOahekxSs5

Why does it work like this? Shouldn’t the 595 just be automatically appended?