How to create new role with same capabilities of existing role.
Eg: I would like to create a new role with same capabilities of administrator or editor and so on..

Try this… This should work.
<?php
add_action('init', 'cloneRole');
function cloneRole()
{
global $wp_roles;
if ( ! isset( $wp_roles ) )
$wp_roles = new WP_Roles();
$adm = $wp_roles->get_role('administrator');
//Adding a 'new_role' with all admin caps
$wp_roles->add_role('new_role', 'My Custom Role', $adm->capabilities);
}
?>
Check it.